WebWe adopt atomistic molecular dynamics (MD) simulations to study the solvation and gelation behavior of homogeneous methylcellulose (MC) and model random oligomers that represent the commercial cellulosic polymer product METHOCEL A in water and acetone solvents. We demonstrate that the two carbohydrate-specific GROMOS force fields, … WebSolvation of sulphonic acid groups in Nafion® membranes from accurate conductivity measurements
Nafion in Dilute Solvent Systems: Dispersion or Solution?
WebApr 21, 2011 · It was found that sulfonate groups influence excess proton solvation, as well as the proton hydration structure, by stabilizing a more Zundel-like (H(5)O(2)(+)) structure in their first solvation shells. Proton solvation properties and transport mechanisms have been studied in hydrated Nafion using the self-consistent multistate empirical valence bond … WebOct 27, 2013 · The Nafion polymers were first introduced in the form of melt-processed membranes or aqueous dispersions by the E. I. DuPont Company in the mid1980s and used as the industrial standard materials for polymer electrolyte fuel cells. Although Nafion and … small china bowls for serving sauces
Proton Solvation and Transport in Hydrated Nafion
Webacid groups present in the Nafion membrane can adopt a spherical structure of inverted micelles about 4 nm in diameter [5]. The water absorbed by Nafion membrane is incorporated into the ionic clus-ters of the sulfonic acid group and the water content in hydrated Nafion membrane can vary up to 22 molecules of water per sulfonic acid group [6]. Web2.1 Introduction. Gelation is a process that is of importance to a wide range of applications in food, pharmaceutical and material sciences. Gelation is a general way to convert a fluid to a solid and has been used since antiquity to produce a variety of foods with distinctive textures. Foods such as gelatin-based desserts are some of the ... WebThe original color of the Nafion™ polymer changes gradually from translucent to yellow, then brown, then even black. The chemical nature of the Nafion™ polymer itself is not changed by this process. The Nafion™ polymer is not directly attacked, and the Nafion™ polymer is not degraded. Its properties of water permeability, ion-exchange ... small china cabinet wood